Can you do an ‘mpc status’ command to confirm the volume is actually 100% and hasn’t been reduced behind the scenes by a frontend? The mixer_volume config is only the initial volume (at startup).
Can you also open alsamixer and confirm that 100% volume in mopidy is 30% in alsamixer. If they both say the volume is 100% then Mopidy-alsamixer has done all it can do and the problem is elsewhere in your system.